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Plastic Pyrolysis

Pyrolysis Reactor with External Furnace

The central machine in a plastic pyrolysis plant — a sealed cylindrical reactor vessel heated indirectly through a refractory furnace shell, operating at 350–550°C without oxygen to thermally crack plastic into oil vapors, syngas, and char.

Hero cross-section diagram of a cylindrical pyrolysis reactor vessel inside a refractory-lined furnace shell, showing the burner firing heat into the annular space between furnace and reactor, the feed auger on the left side of the reactor, vapor outlet pipe on top, sealed char discharge conveyor at the bottom, pressure instrument tag PI, and temperature labels showing 350-550 degrees Celsius operating range with no-oxygen condition inside
Hero cross-section diagram of a cylindrical pyrolysis reactor vessel inside a refractory-lined furnace shell, showing the burner firing heat into the annular space between furnace and reactor, the feed auger on the left side of the reactor, vapor outlet pipe on top, sealed char discharge conveyor at the bottom, pressure instrument tag PI, and temperature labels showing 350-550 degrees Celsius operating range with no-oxygen condition inside
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How to read this sketch

This is a vertical cross-section through the reactor and furnace assembly. Read it as follows:

  • Outer shell (Furnace): The large outer rectangle with hatched lining is the refractory-lined furnace. The burner fires into the annular space between furnace and reactor.
  • Inner vessel (Reactor): The cylinder sitting inside the furnace is the sealed reactor. All pyrolysis chemistry happens inside this vessel.
  • Vapor outlet (top): Arrow pointing up — where cracked vapors exit to the condenser train.
  • Feed auger (left): Screw conveyor moving pre-processed plastic into the reactor.
  • Char discharge (bottom): Sealed screw conveyor removing solid char after cooling.
  • PI tag: Pressure instrument — the critical safety monitor. Normal: 0.05–0.3 bar gauge.
  • Labels: 350–550°C is the reactor temperature range. 'no O₂' confirms the sealed, oxygen-free environment.

About this sketch

The pyrolysis reactor is the heart of the plant — the sealed vessel where plastic is thermally cracked at 350–550°C in the complete absence of oxygen. This diagram shows the most common Indian commercial design: an external furnace approach where the reactor cylinder sits inside a larger refractory-lined furnace shell, and the burner heats the annular gap between the two vessels. Heat transfers through the reactor wall by conduction, never by direct contact with flame.

Indirect heating is a deliberate safety choice. Keeping the open flame outside the reactor ensures that even if a small amount of air enters the reactor shell, it will not come into contact with both heat and plastic vapors simultaneously. The refractory lining of the furnace shell — typically 150–250 mm of high-temperature firebrick or castable refractory — holds the furnace temperature at 400–800°C while the reactor inside reaches its target of 350–550°C.

A feed auger on one side continuously moves pre-processed plastic into the reactor at a controlled rate for continuous units, or the reactor is loaded in batches for batch designs. Inside, long polymer chains thermally crack into shorter hydrocarbon chains as temperature rises. Vapors rise and exit through the vapor outlet at the top and travel to the condenser train. Solid char settles at the bottom and exits via the sealed char discharge — typically a screw conveyor with an airlock to prevent air ingress while hot char is removed.

A pressure instrument (PI) monitors internal pressure continuously. Normal operating pressure is slight positive (0.05–0.3 bar gauge) to prevent air from being drawn in. An automatic shutdown triggers if pressure falls below zero (air ingress risk) or rises above the PRV setpoint (overpressure risk). This instrument tag is the single most critical measurement in the plant.

Key insights

  • External (indirect) heating keeps the open flame separated from plastic vapors inside the reactor — the primary safety design choice for Indian commercial pyrolysis plants.
  • Reactor pressure is maintained at slight positive (0.05–0.3 bar gauge) to prevent air from being drawn in — air plus hot plastic vapors is an explosion risk.
  • Temperature range of 350–550°C is where most plastics (PE, PP, PS) thermally crack; higher temperatures increase gas yield at the expense of oil yield.
  • The sealed char discharge screw prevents air ingress during char removal — discharging while the reactor is still at temperature would cause char to reignite.
  • Refractory lining (150–250 mm) is a significant part of the furnace construction cost — it must be replaced every 5–10 years depending on thermal cycling intensity.

Frequently asked questions

Why do most Indian pyrolysis plants use external (indirect) heating instead of internal heating?

External heating keeps the burner flame completely outside the sealed reactor vessel. If an internal heater were used, a fault could introduce oxygen or ignition into the reactor alongside hot plastic vapors — a combustion or explosion risk. External heating also allows the furnace to run on multiple fuel types (diesel, LPG, syngas) without any modification to the reactor vessel.

What is the correct pressure to maintain inside the reactor during operation?

A slight positive pressure of 0.05–0.3 bar gauge is standard. Positive pressure prevents air from being drawn in through seals or the feed inlet. If pressure drops to zero or negative, the automatic safety interlock should trigger an alarm and close the feed inlet before air reaches the hot plastic mass.

How long does a pyrolysis reactor vessel last?

The reactor vessel itself (typically MS or SS steel, 8–16 mm wall) lasts 5–15 years depending on material quality and operating temperature. The external furnace refractory lining typically needs relining every 5–10 years. Char-side surfaces corrode faster than vapor-side surfaces; regular inspection of the char discharge zone is important.
Last updated: Jun 15, 2026 License
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